Strong dc electric field applied to supersaturated aqueous glycine solution induces nucleation of the gamma polymorph.
نویسندگان
چکیده
Applying a strong static electric field to supersaturated aqueous glycine solutions resulted in the nucleation of the gamma polymorph. This is the first report of a strong dc field inducing the nucleation of a neutral solute in a supersaturated solution. We attribute this effect to the electric-field-induced orientation of the highly polar glycine molecules in large preexisting solute clusters, helping them organize into a crystalline structure. This result also lends further support to our proposed optical-Kerr mechanism for nonphotochemical laser-induced nucleation.
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ورودعنوان ژورنال:
- Physical review letters
دوره 94 14 شماره
صفحات -
تاریخ انتشار 2005